P-P05-K1是什么意思
点击联系发帖人
时间：2020-06-09 13:00
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}
05、06级材料专业《物理化学》期未試卷A （ 学年 第二学期）
一、选择题（每题1分；填上正确答案）（15分） 1、 已知下列两电极反应的标准电极电势为：
△rSm为32.9J?K?mol则电池电动势嘚温度系数
3、在等温、等压下电池以可逆方式对外作电功的热效应为Qr，则： （C）
（A）Qr=0； （B）Qr=△H； （C）Qr=T△S； （ D）Qr=△U 4、弯曲表面上附加压力的計算公式：△p=2σ/r （C）液面为凸面时为负凹面为正；（D）总为负
5、液体在毛细管中上升的高度与下列哪一个因素无关： （D） （A）温度； （B）液体密度； （C）重力加速度； （D）大气压力 6、两个活化能不同反应，如 （A）dlnk2/dT > dlnk1/dT；
E1>E2且都在相同的升温区间内升温，则（B）
中r的符号： （A）
（A）液面为凸面时为正，凹面为负；（B）总为正；
7、有关基元反应的描述在下列诸说法中哪一个是不正确的 （D） （A）元反应的级数一萣是整数；（B）元反应的级数一般不大于3 （C）元反应进行时无中间产物；（D）元反应不一定符合质量作用定律 8、某二级反应，反应物消耗1/3需时10min若再消耗1/3还需时为： （C）
9、温度与表面张力的关系是： （A）
（A）温度升高表面张力降低； （B）温度升高表面张力增加； （C）温度对表面张力没有影响； （D）不能确定。 10、对于反应A（A）
Y如果反应物A的浓度减少一半，A的半衰期也缩短一半则该反应的级数为：
（A）零级； （B）一级； （C）二级； （D）三级 11、在反应
D中，活化能 E1>E2>E3C是所需要的产物，从动力学角度考虑
为了提高C的产量，温度如何选择： （A）
(A)较高反应温度； (C)适中反应温度；
(B)较低反应温度 (D)任意反应温度
12、质量摩尔浓度为b的K3PO4溶液离子平均活度因子为γ±，则电解质的活度是aB：
（A）表面吉布斯自由能降低的过程； （B）表面吉布斯自由能增加的过程； （C）表面吉布斯自由能不变的过程； （D）表面积缩小的过程。
15、今有┅球形肥皂泡半径为r，肥皂水溶液的表面张力为σ，则肥皂泡内附加压力是： （C） （A）?p?2??4?； （B）?p?； （C）?p?； （D）r2rr
二、判断题（每题1分；对打√错打×）（10分）
1、液体的表面张力的存在力图扩大液体的表面积。 (×) 2、化学吸附无选择性 (×) 3、原电池的正极即为阳极，负极即为阴極 (×) 4、光的量子效率不可能大于1。 (×) 5、零级反应的半衰期为 c A , 0 (√)
8、活化能数据在判断反应机理时的作用之一是在两状态之间若有几条能峰不同的途径，从统计意义来讲, 过程总是沿着能峰最小的途径进行（√）
9、用?m对c作图外推方法，可求得NaAc的无限稀释摩尔电导率（√） 10、在临界胶束浓度（CMC）前后溶液的表面张力有显著变化。 （×） 三、填空题（每题1分在题中“____”处填上答案）（15分）
1、 纯水、盐水、皂液相比，其表面张力的排列顺序是σ（盐水） > σ（水） > σ（皂液）。（选填 ）
2、判别溶胶与溶液的最简便的方法是 Tyndall效应
3、对反应AP，实验測得反应物的半衰期与与初始浓度cA,0成反比则该反应为 二 级反应。 4、Tyndall效应是因为光的 散射作用 而产生的 5、溶胶粒子的半径一般在 1~100nm 之间。
6、ζ 电势与热力学电势φ0不同φ0的数值主要取决于总体上溶液中与固体成平衡的 离子浓度 ；而ζ电势则随着溶剂化层中 离子的浓度 而改變，少量外加电解质对ζ电势的数值会有 显著影响 甚至可以改变其 符号 。
7、液体表面张力的方向总是 沿液体表面的切线方向 ； 液体表面汾子所受合力的方向总是 沿液体表面的法线方向指向液体内部 。 8、反应A + BY的速率方程为：
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